OIL CHANGES (Part 1): Oil Breakdown
IRST, ALL OIL BREAKS DOWN.
That generally will include basestocks and additives.
Without focusing on performance characteristics, the most
significant difference from one oil to another is how
quickly breakdown occurs.
Although there are many factors
that contribute to the breakdown of an oil, heat is one of
the most important. Depletion and decreased effectiveness
of oil additives is also important, but that will be
discussed later.
Petroleum oil begins to
break-down almost immediately. A high quality synthetic, on
the other hand, can last for many thousands of miles
without any significant reduction in performance or
protection characteristics. Synthetics designed from the
right combination of basestocks and additives can last
indefinitely with the right filtration system.
As alluded to above, the first
major difference between petroleum and synthetic oil is
heat tolerance. Flash point is the temperature at which an
oil gives off vapors that can be ignited with a flame held
over the oil. The lower the flash point the greater
tendency for the oil to suffer vaporization loss at high
temperatures and to burn off on hot cylinder walls and
pistons. The flash point can be an indicator of the quality
of the base stock used. The higher the flash point the
better. 400 degrees F is the minimum to prevent possible
high consumption.
Today’s engines are
expected to put out more power from a smaller size and with
less oil than engines of the past. Therefore, the engines
run much hotter than they used to. That puts an increased
burden on the oil.
Even the best petroleum oils
will have flash points only as high as 375 and 420 degrees
F. For today’s hot running engines, this may not be
nearly enough protection. Just about any synthetic you come
across will have a flash point over 430 degrees. High
quality synthetics can have flash points over 450 degrees
(Every
AMSOIL synthetic oil has a flash point of over 450
degrees F with some exceeding 475 degrees). As a result,
you will see little noticeable breakdown due to
burn-off.
Just as important is the way in
which petroleum and synthetic oils burn off. As a refined
product, petroleum oils molecules are of varying sizes.
Thus, as a petroleum oil heats up, the smaller molecules
begin to burn off. Since the ash content in most petroleum
oils is very high, deposits and sludge are left behind to
coat the inside of your engine. In addition, as smaller
particles burn off, the larger, heavier molecules are all
that is left to protect the engine. Unfortunately, these
larger particles do not flow nearly as well and tend to
blanket the components of your engine which only
exacerbates the heat problem.
Synthetic oils, because they
are not purified, but rather designed specifically from the
ground up for lubrication purposes, are comprised of
molecules of uniform size and shape. Therefore, even if a
synthetic oil does burn a little, the remaining oil has the
same chemical characteristics that it had before the burn
off. There are no smaller molecules to burn-off and no
heavier molecules to leave behind. Moreover, many
synthetics, have very low ash content. As a result, if oil
burn-off does occur, there is little or no ash left behind
to leave sludge and deposits on engine surfaces. Obviously,
this leads to a cleaner burning, more fuel efficient
engine.
As a side note (as it really
has little bearing on when to change your oil), synthetics
do a much better job of “cooling” engine
components during operation. Because of their unique flow
characteristics, engine components are likely to run 10 to
30 degrees cooler than with petroleum oils. This is
important, because the hotter the components in your engine
get, the more quickly they break down.
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